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Aluminium magnesium boride : ウィキペディア英語版
Aluminium magnesium boride
Aluminum magnesium boride or BAM is a chemical compound of aluminium, magnesium and boron. Whereas its nominal formula is AlMgB14, the chemical composition is closer to Al0.75Mg0.75B14. It is a ceramic alloy that is highly resistive to wear and has a low coefficient of sliding friction, reaching a record value of 0.02 in lubricated AlMgB14−TiB2 composites. First reported in 1970, BAM has an orthorhombic structure with four icosahedral B12 units per unit cell.〔 This ultrahard material has a coefficient of thermal expansion comparable to that of other widely used materials such as steel and concrete.
==Synthesis==
BAM powders are produced by heating a nearly stoichiometric mixture of boron, aluminium and magnesium for a few hours at a temperature in the range 900–1500 °C. Spurious phases are then dissolved in hot hydrochloric acid.〔〔 To ease the reaction and make the product more homogeneous, the starting mixture can be processed in a high-energy ball mill. All pretreatments are carried out in a dry, inert atmosphere to avoid oxidation of the metal powders.〔〔
BAM films can be coated on silicon or metals by pulsed laser deposition, using AlMgB14 powder as a target,〔 whereas bulk samples are obtained by sintering the powder.〔
BAM usually contains small amounts of impurity elements (e.g., oxygen and iron) that enter the material during preparation. It is thought that the presence of iron (most often introduced as wear debris from mill vials and media) serves as a sintering aid. BAM can be alloyed with silicon, phosphorus, carbon, titanium diboride (TiB2), aluminium nitride (AlN), titanium carbide (TiC) or boron nitride (BN).〔〔

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